MPLS is the core technology that run service provider and large enterprise networks on a daily basis. These resources cover the major technologies utilized.
Resources in Recommended Order
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Day One MPLS for Enterprise Engineers (General introduction to concepts)
This is a free pdf download but you must create an account for the Juniper forums site.
https://forums.juniper.net/t5/Day-One-Books/Day-One-MPLS-for-Enterprise-Engineers/ba-p/232940
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This Week Deploying MPLS (More detailed introduction)
This is a free pdf download but you must create an account for the Juniper forums site.
https://forums.juniper.net/t5/Day-One-Books/This-Week-Deploying-MPLS/ba-p/87830
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Metro Ethernet Design Guide (Best practices)
https://www.juniper.net/documentation/en_US/release-independent/solutions/information-products/pathway-pages/solutions/metro-ethernet-dg.pdf
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Ethernet OAM Overview (this is the service assurance process)
Ethernet_OAM -
MPLS Applications Feature Guide (detailed configuration examples)
https://www.juniper.net/documentation/en_US/junos/information-products/pathway-pages/config-guide-mpls-applications/config-guide-mpls-applications.pdf
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Using G.8032 Ethernet Stitching in a Mixed Environment (this is how to connect vlan standards based rings into an MPLS network)
https://www.juniper.net/documentation/en_US/release-independent/solutions/information-products/pathway-pages/G.8032-Eth-VPLS-stitching.pdf